The European Champions and current Super Cup holder will play the first game of Champions League on the verge of retaining their title.
Real Madrid will take on Borussian Dortmond, Sporting Lisbon and Legia Warsaw in group f of the Champions League.
The group stage will kick off on 13th and 14th of september, and will come to an end on the 6th and 7th of December.
The final of the season champion league will be played at Millenium Stadium in Cardiff on the 3rd of June 2017.
Champions League Group Table
Group A: PSG, Arsenal, Basel and Ludogorets.
Group B: Benfica, Napoli, Dynamo Kiev and Besiktas.
Group C: Barcelona, Manchester City, Borussia Mochengladbach
Group D Bayer Munich, Atletico Madrid, PSV and Rostov
Group E: CSKA Moscow, Bayern Leverkusen, Tottenham and Moncaco
Group F: Ream Madrid, Borussia Dortmund, Sporting Lisbon and Legia Warsaw
Group G: Leicester City, Porto, Club Brugge and FC Copenhagen
Group H: Juventus, Sevilla, Lyon and Dinamo Zagreb